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Structure-Reactivity Correlations and Organic Reaction Mechanisms

XL0.9 Structure-Reactivity Correlations and Organic Reaction Mechanisms · XL0: Chemistry (Common for all XL candidates)

CHEM.ORGANIC Chemistry

Structure-reactivity relationships, stereochemistry, and the mechanisms of substitution, elimination and addition.

16 sub-topics

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01

Acids and bases

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02

electronic and steric effects

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03

stereochemistry

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04

optical and geometrical isomerism

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05

tautomerism

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06

conformers and concept of aromaticity

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07

elementary treatment of SN1, SN2, E1, E2 and radical reactions

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08

Hoffmann and Saytzeff rules

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09

addition reactions

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10

Markownikoff rule and Kharasch effect

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11

elementary hydroboration reactions

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12

Grignard's reagents and their uses

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13

aromatic electrophilic substitutions

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14

nucleophilic aromatic substitutions

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15

orientation effect as exemplified by various functional groups

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16

identification of common functional groups by chemical tests

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